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10.1016/j.neuroscience.2022.06.038 Neuroscience 12 BenarrochE

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Highlighting the utility of thiophenol thioesters as an alternate to acyl-SNACs, Sherman and coworkers synthesized the hexaketide thiophenol thioester to prime module 5 of the juvenimyicin PKS in their efforts to chemoenzymatically synthesize juvenimicin and rosamicin macrolides