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Potential mechanism of emphysema: alpha-1 proteinase inhibitor recovered from lungs of cigarette smokers contains oxidized methionine and has decreased elastase inhibitory capacity
In: Kramer K, Hoppe P, Packer L, eds
monocytogenes and S
PolyLC)
doi: 10.1152/ajpcell.1995.269.6.C1371
Comparison to a synthetic standard supported the annotation of this peak as 4-bromonicotinic acid, although differences in fragment ion intensity between the synthetic and experimental MS/MS spectra meant that without access to the original sample, this structure remained a leading hypothesis rather than a definitive identification
