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They are related but different copper peptides

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Calcium- and endothelial-mediated vascular smooth muscle relaxation in rabbit aorta
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Citrulline plays a crucial role in the urea cycle and serves as a precursor to L-arginine, which is subsequently converted into nitric oxide (NO), a key vasodilator involved in maintaining vascular tone, endothelial function, and blood pressure regulation [8]
It is the reason their results stay consistent month after month while others wonder why potency drops after two weeks in the fridge